(N,N-Diallyldithiocarbamato-κ2 S,S′)triphenyltin(IV) and bis(N,N-diallyldithiocarbamato-κ2 S,S′)diphenyltin(IV): crystal structure, Hirshfeld surface analysis and computational study
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چکیده
منابع مشابه
fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ2 S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis
The title compound, [Re(C3H6NS2)(C2H3N)(CO)3], features an octa-hedrally coordinated ReI atom within a C3NS2 donor set defined by three carbonyl ligands in a facial arrangement, an aceto-nitrile N atom and two S atoms derived from a symmetrically coordinating di-thio-carbamate ligand. In the crystal, di-thio-carbamate-methyl-H⋯O(carbon-yl) inter-actions lead to supra-molecular chains along [36-...
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The asymmetric unit of the title complex, [Zn3(C7H5O2)6(C6H4N2)2], contains one half of the complex mol-ecule, i.e. one and a half ZnII cations, three benzoate (Bnz) and one pyridine-3-carbo-nitrile (Cpy) mol-ecule; the Bnz anions act as bidentate ligands through the carboxyl-ate O atoms, while the Cpy ligand acts as a monodentate N(pyridine)-bonding ligand. The complete centrosymmetric trinucl...
متن کاملDi-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
The complete mol-ecule of the title compound, [Sn(C4H9)2(C5H10NOS2)2], is generated by a crystallographic mirror plane, with the SnIV atom and the two inner methyl-ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di-thio-carbamate ligand coordinates to the metal atom in an asymmetr...
متن کاملSecondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2 S,S′)tin(IV): crystal structure and Hirshfeld surface analysis
The title compound, [Sn(CH3)2(C5H8NOS2)2], has the SnIV atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating di-thio-carbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the mol-ecular packing are secondary Sn⋯S inter-actions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dim...
متن کامل[N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2 S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis
The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamates, [Sn(C6H5)3(C16H16NS2)], (I), and [Sn(C6H5)3(C7H14NO2S2)], (II), are described. In (I), the di-thio-carbamate ligand coordinates the SnIV atom in an asymmetric manner, leading to a highly distorted trigonal-bipyramidal coordination geometry defined by a C3S2 donor set with the weakly bound S atom approximately trans ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications
سال: 2020
ISSN: 2056-9890
DOI: 10.1107/s2056989020000122